http://www.sevenforums.com/tutorials/419-run-different-user.html

Windows 7 - Run as Different User

1. Press and hold the Shift key and right click on the program's shortcut or EXE file, then click on Run as different user. (See screenshot below)

password of the user account that you want to run this program as. (See screenshot below)
4. When done, simply close the program to stop it from running as that user.
That's it,

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