聚酞菁钴和碳纳米管复合材料用于电还原催化剂
借助于碳纳米管特有的一维结构特点，利用酞菁钴聚合物与碳纳米管复合后产生的协同作用，大大提高了聚酞箐钴的导电性和电催化活性位点数量，加快了电催化还原CO2的动力学过程，从而获得了更佳的电催化性能。研究结果表明，该催化剂还原CO2的起始过电位可以和贵金属Au，Ag媲美，CO2转化生成CO的法拉第效率高达90%，且在相同过电势下的催化转化频率(TOF)超过了目前绝大多数有机或无机催化材料。此外，该催化剂能够维持长达24小时以上的电催化性能。
采用简单的原位聚合方法制备出聚酞箐钴/碳纳米管（CoPPc/CNT）复合材料。他们运用扫描电子显微镜(SEM)和透射电子显微镜(TEM)的方法表征了复合材料的化学组成和形貌。结果显示，生成的CoPPc/CNT保持了碳纳米管原有的一维结构，且聚酞菁钴在碳纳米管外壁形成了一层厚度均匀的聚合物层（图二）。研究者们利用拉曼(Raman)、红外(FT-IR)、紫外可见吸收(UV-vis)、同步辐射(XANES、EXAFS)等光谱分析手段进一步分析了复合材料的化学结构 (图三)。综合上述结果，此模板导向聚合的方法能够成功地制备出聚酞菁钴和碳纳米管有机-无机复合结构，得到了充分证实。区别于传统的大环分子与碳材料相互间的共价或非共价的键连方式，该工作中采用的模板导向聚合作用能够大大提高有机相的物理化学稳健性。
图二. CoPPc/CNT催化剂的制备流程及结构表征，包括SEM,TEM，HAADF以及EDS mapping
| 产品名称 | 别名 | 英文名称 | cas |
| 酞菁二锂 | Phthalocyanine Dilithium | 25510-41-2 | |
| 5,10,15,20-四苯基-21H,23H-卟啉锌(II) 锌(II)TPP |
四苯基卟啉锌(II) | 5,10,15,20-Tetraphenyl-21H,23H-porphine Zinc(II) Zinc(II) TPP |
14074-80-7 |
| 2,3,7,8,12,13,17,18-八乙基卟啉 | 2,3,7,8,12,13,17,18-八乙基-21H,23H-卟吩 | 2,3,7,8,12,13,17,18-Octaethylporphyrin | 2683-82-1 |
| 二氯酞菁锡(IV) | 酞菁二氯化锡(IV) | Tin(IV) Phthalocyanine Dichloride | 18253-54-8 |
| 酞菁二钠 | Disodium Phthalocyanine | 25476-27-1 | |
| 5,10,15,20-四(2,4,6-三甲苯基)卟啉 | 5,10,15,20-四(2,4,6-三甲苯基) -21H,23H-卟吩 | 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)porphyrin | 56396-12-4 |
| 5,9,14,18,23,27,32,36-八丁氧基-2,3-萘酞菁铜(II) 铜(II)-5,9,14,18,23,27,32,36-八丁氧基-2,3-萘酞菁 |
5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine Copper(II) | Copper(II) 5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine | 155773-67-4 |
| 四苯基卟啉氯化铁(III) | 5,10,15,20-四苯基-21H,23H-卟啉氯化铁(III) 5,10,15,20-Tetraphenyl-21H,23H-porphine Iron(III) Chloride |
Iron(III) Tetraphenylporphyrin Chloride | 16456-81-8 |
| 酞菁铁(II) (升华提纯) | Phthalocyanine Iron(II) (purified by sublimation) | Iron(II) Phthalocyanine (purified by sublimation) | 132-16-1 |
| [5-[双(4-己基苯基)氨基]-15-[2-(4-羧基苯基)乙炔基]-10,20-双(3,5-二-叔丁基苯基)卟啉]合锌(II) | YD2 | [5-[Bis(4-hexylphenyl)amino]-15-[2-(4-carboxyphenyl)ethynyl]-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) | 1201915-91-4 |
| 酞菁锡(II) | Phthalocyanine Tin(II) | Tin(II) Phthalocyanine | 15304-57-1 |
| 酞菁镁(II) | Phthalocyanine Magnesium(II) | Magnesium(II) Phthalocyanine | 1661-03-6 |
| 5,10,15,20-四(2,6-二氯苯基)卟吩 | 5,10,15,20-四(2,6-二氯苯基)卟啉 | 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin | 37083-37-7 |
| 2,3,7,8,12,13,17,18-八氟-5 ,10,15,20-四(五氟苯基)卟啉 | 全氟-5,10,15,20-四苯基-21H,23H-卟啉 | 2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin | 121399-88-0 |
| 酞氰化锌 (升华提纯) | 酞菁锌 | Zinc Phthalocyanine (purified by sublimation) | 14320-04-8 |
| 5,15-二苯基卟啉 | 5,15-二苯基-21H,23H-卟吩 | 5,15-Diphenylporphyrin | 22112-89-6 |
| 酞菁铅(II) | Phthalocyanine Lead(II) | Lead(II) Phthalocyanine | 15187-16-3 |
| 酞菁钴(II) (升华提纯) | Cobalt(II) Phthalocyanine (purified by sublimation) | 3317-67-7 | |
| 2,3,9,10,16,17,23,24-八氟酞菁铜(II) (升华纯化) | 2,3,9,10,16,17,23,24-Octafluorophthalocyanine Copper(II) (purified by sublimation) F8CuPc (purified by sublimation) |
Copper(II) 2,3,9,10,16,17,23,24-Octafluorophthalocyanine (purified by sublimation) | 148651-60-9 |
| 2,9,16,23-四叔丁基酞菁铜(II) | 4,4',4',4'-四叔丁基酞菁铜 | Copper(II) 2,9,16,23-Tetra-tert-butylphthalocyanine | 39001-64-4 |
| 四苯基卟啉钴(II) | 5,10,15,20-四苯基-21H,23H-卟吩钴(II) TPP钴(II) |
Cobalt(II) Tetraphenylporphyrin | 14172-90-8 |
| 四苯基卟啉铜(II) | 5,10,15,20-四苯基-21H,23H-卟啉铜(II) 铜(II)TPP |
Copper(II) Tetraphenylporphyrin | 14172-91-9 |
| 酞菁氯化铝 | 铝酞菁 | Phthalocyanine Chloroaluminum | 14154-42-8 |
| 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-十六氟酞菁铜(II) (升华提纯) | F16CuPc (purified by sublimation) | 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-Hexadecafluorophthalocyanine Copper(II) (purified by sublimation) | 14916-87-1 |
| 酞菁蓝 | 酞菁铜(II),90%（β型） | Phthalocyanine Blue | 147-14-8 |
| 颜料蓝16 (升华提纯) | Pigment Blue 16 (purified by sublimation) | Phthalocyanine (purified by sublimation) | 574-93-6 |
| 5,10,15,20-四(4-羧基甲氧苯基)-卟啉 | 5,10,15,20-四(4-羧基甲氧苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin | 127812-08-2 |
| 5,10,15,20-四(对甲苯基)卟啉 | 5,10,15,20-四(4-甲苯基)卟啉 | 5,10,15,20-Tetrakis(p-tolyl)porphyrin | 14527-51-6 |
| 5,10,15,20-四(4-羟苯基)卟啉 | 5,10,15,20-四(4-羟苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin | 51094-17-8 |
| 5,10,15,20-四(3,5-二甲氧苯基)卟啉 | 5,10,15,20-四(3,5-二甲氧苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin | 74684-34-7 |
| 内消旋-四苯基卟吩 | meso-Tetraphenylchlorin | 2669-65-0 | |
| meso-四(4-羧基苯基)卟吩四甲酯 | 5,10,15,20-四(4-甲氧羰基苯基)卟啉 | 5,10,15,20-Tetrakis(4-methoxycarbonylphenyl)porphyrin | 22112-83-0 |
| 5,10,15,20-四(4-氨基苯基)卟啉 | 5,10,15,20-四(4-氨基苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(4-aminophenyl)porphyrin | 22112-84-1 |
| 5-(4-羧苯基)-10,15,2-三苯基卟啉 | 5-(4-羧苯基)-10,15,2-三苯基-21H,23H-卟吩 | 5-(4-Carboxyphenyl)-10,15,20-triphenylporphyrin | 95051-10-8 |
| 5,10,15,20-四(五氟苯基)卟啉 | 5,10,15,20-四(五氟苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin | 25440-14-6 |
| 5,10,5,20-四(3,5-二羟苯基)卟啉 | 5,10,5,20-四(3,5-二羟苯基) -21H,23H-卟吩 | 5,10,15,20-Tetrakis(3,5-dihydroxyphenyl)porphyrin | 145764-54-1 |
| 酞菁绿G | 颜料绿 7 | Pigment Green 7 | 1328-53-6 |
| 5,15-双(苯乙炔基)-10,20-双[(三异丙基硅烷基)乙炔基]卟吩]]合镁(II) | [5,15-Bis(phenylethynyl)-10,20-bis[(triisopropylsilyl)ethynyl]porphyrinato]magnesium(II) | 1397288-30-0 | |
| 锡(IV) 2,3-二氯化萘酞菁 | 二氯(2,3-萘酞氰基)锡(IV) | Tin(IV) 2,3-Naphthalocyanine Dichloride | 26857-61-4 |
| 5,10,15,20-四(4-甲氧苯基)-21H,23H-卟吩 | 5,10,15,20-四(4-甲氧苯基)卟啉 | 5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrin | 22112-78-3 |
| 氧钛酞菁 (升华提纯) | 酞菁氧钛/氧化(酞菁)钛 | Titanyl Phthalocyanine (purified by sublimation) | 26201-32-1 |
| 四苯基卟吩 | Tetraphenylporphine (Chlorin free) TPP (Chlorin free) |
Tetraphenylporphyrin (Chlorin free) | 917-23-7 |
| 5-(4-甲氧羰基苯基)-10,15,2-三苯基卟吩 | 5-(4-Carbomethoxyphenyl)-10,15,20-triphenylporphyrin | 5-(4-Methoxycarbonylphenyl)-10,15,20-triphenylporphyrin | 119730-06-2 |
| [5,10,15,20-四(4-甲氧苯基)卟啉]合钴(II) | [5,10,15,20-四(4-甲氧苯基)-21H,23H-卟吩]合钴(II) 卟啉钴 |
[5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato]cobalt(II) | 28903-71-1 |
| 5,10,15,20-四(4-吡啶基)卟啉 | 5,10,15,20-四(4-吡啶基)-21H,23H-卟啉 | 5,10,15,20-Tetra(4-pyridyl)porphyrin | 16834-13-2 |
| 四(4-羧苯基)卟吩 | TCPP [=四(4-羧苯基)卟吩] [铜和镉用超高灵敏分光光度试剂][用于以HPLC进行的金属同时测定] | Tetrakis(4-carboxyphenyl)porphyrin | 14609-54-2 |
| 5,10,15,20-四(4-磺苯基)卟啉 四苯基卟啉四磺酸 |
TPPS (=四苯基卟啉四磺酸水合物) | 5,10,15,20-Tetrakis(4-sulfophenyl)porphyrin Tetraphenylporphyrin Tetrasulfonic Acid |
35218-75-8 |
| 二氰基吡嗪类&类似物 [酞菁砌块] | |||
| 2-氨基-4,5-二氰基-1H-咪唑 | 2-氨基-4,5-咪唑二甲腈 | 2-Amino-4,5-dicyano-1H-imidazole | 40953-34-2 |
| 1,4,5,6-四氢-5,6-二氧-2,3-二氰基吡嗪 | 1,4,5,6-四氢-5,6-二氧-2,3-吡嗪二甲腈 | 1,4,5,6-Tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile | 36023-64-0 |
| 5,6-二氨基-2,3-二氰基吡嗪 | 2,3-二氰基-5,6-二氨基吡嗪 | 5,6-Diamino-2,3-dicyanopyrazine | 36023-58-2 |
| 2,3-二氰基-5-甲基吡嗪 | 5-Methyl-2,3-pyrazinedicarbonitrile | 2,3-Dicyano-5-methylpyrazine | 52197-12-3 |
| 吡啶-2,3-二甲腈 | 2,3-二氰基吡啶 | Pyridine-2,3-dicarbonitrile | 17132-78-4 |
| 2,3-二氰基吡嗪 | 吡嗪-2,3-二甲腈 | 2,3-Dicyanopyrazine | 13481-25-9 |
| 4,5-二氰基咪唑 | DCI/4,5-二氰咪唑 | 4,5-Dicyanoimidazole | 1122-28-7 |
| 5,6-二氯-2,3-二氰基吡嗪 | 5,6-Dichloro-2,3-pyrazinedicarbonitrile | 5,6-Dichloro-2,3-dicyanopyrazine | 56413-95-7 |
| 2,3-二氰基-5-氨基-6-氯吡嗪 | 5-氨基-6-氯-2,3-二氰基吡嗪 | 5-Amino-6-chloro-2,3-dicyanopyrazine | 56413-96-8 |
| 邻苯二甲腈类 [酞菁砌块] | |||
| 4-硝基邻苯二甲腈 | 1,2-二氰基-4-硝基苯 | 4-Nitrophthalonitrile | 31643-49-9 |
| 1,3-二亚氨基异吲哚啉 | 1,3-Diiminoisoindoline | 57500-34-2 | |
| 4-碘酞腈 | 1,2-二氰基-4-碘苯 | 4-Iodophthalonitrile | 69518-17-8 |
| 3-硝基邻苯二甲腈 | 1,2-二氰基-3-硝基苯 | 3-Nitrophthalonitrile | 51762-67-5 |
| 4-(4-α-异丙苯基苯氧基)苯二甲腈 | 2-[4-(3,4-Dicyanophenoxy)phenyl]-2-phenylpropane | 4-(4-α-Cumylphenoxy)phthalonitrile | 83482-57-9 |
| 4-戊氧基苯二甲腈 | 4-戊氧基邻苯二甲腈 | 4-Pentyloxyphthalonitrile | 106943-83-3 |
| 4-溴邻苯二甲腈 | 4-溴-1,2-二氰基苯 | 4-Bromophthalonitrile | 70484-01-4 |
| 4-正丁氧基-1,2-二氰苯 | 4-丁氧基邻苯二甲腈 | 4-Butoxyphthalonitrile | 81560-32-9 |
| 4-己氧基苯二甲腈 | 1,2-Dicyano-4-hexyloxybenzene | 4-Hexyloxyphthalonitrile | 104949-82-8 |
| 4-丙氧基邻苯二甲腈 | 4-丙氧基苯二甲腈 | 4-Propoxyphthalonitrile | 106144-18-7 |
| 4-氨基邻苯二甲腈 | 3,4-二氰基苯胺 | 4-Aminophthalonitrile | 56765-79-8 |
| 1,2-二氰基-4-氟苯 | 4-氟邻苯二腈 | 4-Fluorophthalonitrile | 65610-14-2 |
| 4,5-二氟酞腈 | 1,2-二氰基-4,5-二氟苯 | 4,5-Difluorophthalonitrile | 134450-56-9 |
| 4,5-二氨基酞腈 | 1,2-二氨基-4,5-二氰基苯 | 4,5-Diaminophthalonitrile | 129365-93-1 |
| 4-(2',6'-二甲基苯氧基)邻苯二甲腈 | 1,2-二氰基-4-(2',6'-二甲基苯氧基)苯 | 4-(2',6'-Dimethylphenoxy)phthalonitrile | 221302-75-6 |
| 4,5-二氯邻苯二甲腈 | 1,2-二氯-4,5-二氰基苯 | 4,5-Dichlorophthalonitrile | 139152-08-2 |
| 邻苯二甲腈 | 1,2-二氰基苯 | Phthalonitrile | 91-15-6 |
| 全氯邻苯二甲腈 | 四氯邻苯二甲腈 | Tetrachlorophthalonitrile | 1953-99-7 |
| 4-叔丁基邻苯二甲腈 | 4-叔丁基-1,2-二氰基苯 | 4-tert-Butylphthalonitrile | 32703-80-3 |
| 四氟邻苯二甲腈 | 3,4,5,6-四氟邻苯二甲腈 | Tetrafluorophthalonitrile | 1835-65-0 |
| 4-羟基邻苯二甲腈 | 3,4-二氰基苯酚 | 4-Hydroxyphthalonitrile | 30757-50-7 |
| 1,2-Dicyano-4-dodecyloxybenzene | 4-十二烷氧基邻苯二甲腈 | 4-Dodecyloxyphthalonitrile | 161082-75-3 |
| 1,2,4,5-四氰基苯 | 1,2,4,5-苯四甲腈 | 1,2,4,5-Tetracyanobenzene | 712-74-3 |
| 2,3-二氰基对苯二酚 | 3,6-二羟基邻苯二甲腈 2,3-二氰基羟基醌 3,6-二羟基邻苯二腈 3,6-二羟基邻苯二甲氰 2,3-二氰基氢醌 |
2,3-Dicyanohydroquinone | 4733-50-0 |
| 萘二甲腈类 [酞菁砌块] | |||
| 1,2-萘二甲腈 | 1,2-二氰基萘 | 1,2-Naphthalenedicarbonitrile | 19291-76-0 |
| 1,3-二亚氨基苯并[f]异吲哚啉 | 1,3-Diiminobenz[f]isoindoline | 65558-69-2 | |
| 2,3-二氰基-6-硝基萘 | 2,3-Dicyano-6-nitronaphthalene | 184026-06-0 | |
| 2,3-二溴-6,7-二氰基萘 | 6,7-Dibromonaphthalene-2,3-dicarbonitrile | 2,3-Dibromo-6,7-dicyanonaphthalene | 74815-81-9 |
| 2,3-二氰基-1,4-二羟基-5-硝基萘 | 2,3-二氰基-5-硝基-1,4-萘二醇 | 2,3-Dicyano-1,4-dihydroxy-5-nitronaphthalene | 4655-62-3 |
| 6-溴-2,3-二氰基萘 | 6-溴萘-2,3-二甲腈 | 6-Bromo-2,3-dicyanonaphthalene | 70484-02-5 |
| 2,3-二氰基萘 | 2,3-萘二甲腈 | 2,3-Dicyanonaphthalene | 22856-30-0 |
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